Media Stereotyping

IndividualFinal Project| Write a 1,400- to 1,750-word paper that answers the following questions: * In what ways does the media perpetuate stereotyping and prejudice? Provide examples to support your assertion. * In what ways does the media help foster appreciation for diversity? Provide examples to support your assertion. * How might individuals and the United States work together to reduce prejudice and increase appreciation for diversity? * How might you change your own behaviors to be more inclusive and pluralistic? | Day 7| 10| ————————————————- *In what ways do the media perpetuate stereotyping and prejudice? Provide examples to support your assertion. America is a relatively young country born in war and to this day continues to struggle with its identity. What makes this country strong is the ideals of freedom and equality. â€Å"We hold these truths to be self-evi dent that all men are created†. This is the ideal makes America strong, that no matter where you come from rich or poor that you as an American can achieve the American dream. We have had our struggles, but that is what makes us strong. It is not been an easy journey, we have paid dearly for our freedoms and our way of life.Some people have paid more than others to struggle for the freedoms guaranteed from being an American. Diversity can be traced all the same lines as civil rights movement in America. There is been a fierce battle for independence of different peoples spread across this land. From the deep South and the marches of Martin Luther King Jr. to the Northeast and the persecution of the Puritans. The Southwest has become the new battleground for diversity with the battle against illegal immigration. Some of the information about diversity United States is on display at the Smithsonian Institute in Washington DC.To truly understand the struggles of the civil rights movement and the role of diversity in the southern states throughout the 50s and 60s, you really have to go and see the bus seat of Rosa Parks. You have to see the soda fountain counter and the fire hose used to what a young black man down the street in Birmingham Alabama. I think that the most important point about diversity and one that cannot be silenced as the voices of the people that live this struggle every day, and the forums like this class that bring people from all walks of life from around the globe together to expose the ignorance of racism and prejudice and discrimination.Have you learned something new about your own racial, ethnic, or cultural history? * My history is of Irish decent we came to America for better life. We paid that price in hard work and blood. We came here as indentured servants that we had to work our way to freedom, never once was the American dream promised to us we earned everything. I think that the struggle that we had to go through game us a s ense of pride in America. It was the Chinese and the Irish that built the railroads across this country. We dug the coal that fired the furnaces of the steel mills and we came from places like Hell's kitchen New York City.What this forum has done for me has given me a sense of pride that just not the Irish and the Chinese struggle for the freedom but it seems as if all of the in one way or another had to fight for everything that we have accomplished. Trends in immigration will continue to shape the demographics of the United States. What will the U. S. population look like in the year 2050? Why do you think so? Everybody around the world wants what America has because we have the ideals of freedoms and the dreams of success the great immigration to America will continue.At the present time America has about 20 million immigrants from Mexico and South America. As economies of Third World country continue to deteriorate more and more people will come to America. Everybody wants what America has but because of the agendas of Third World country politicians and the corruption of governments and the war over illegal criminal activities the safe haven of America will still be the priority of people around the world. The demographics of the United States we will continue to move to a change in diversity from a white majority to really know majority at all.The Hispanic population continues to grow in America while the white population continues to decline. The African-American population has already moved from the largest minority to the second largest minority be replaced by the Hispanic minority. If this trend continues by 2050 we can see the Hispanic population become the majority of the largest minority and other people who have not had to fight for civil rights may now find themselves as a beneficiary of those civil rights battles fought by other minorities. What challenges does the United States face due to the diversity of its people? The first issue that come s to mind is language.If the Hispanic population becomes a majority will we see a change in the language that is not only taught but spoken in America. Many merchants and government agencies now speak Spanish as well as English. The challenge of communication is going to be getting everyone on the same sheet of music. I recently been into a store that is predominantly Hispanic and many of the labels are printed in Spanish I have also been a store where the labels are printed in Arabic in order for America to maintain diversity without separation we will have to have a common language that is spoken and written by everyone.Any area of civil rights those court cases that were settled with the idea of a white majority and other minorities may now be referred as a white majority will find itself as a minority. So with that in mind will we see affirmative action for white people? What will be the reaction of the minorities and those court cases are turned around and used against them. Wh at are the benefits of such a diverse society? The benefits of a diverse society is one that a brings equality everyone. With a more diverse society we should not see the need for racial, sexual or disability court cases.More diverse society will be a more understanding society by that I mean that we should not have to force a building or company to put in a wheelchair ramp it will simply be understood that one is needed. The more understanding society will bring about the benefits of less crime less people in prison which will save us all tax dollars and the burdens that are put upon society by hate crimes. The benefits of this society will only continue to get better as the ignorance of discrimination is eliminated from our mindset.How can we foster a climate of acceptance and cultural pluralism in the United States? * The foster a climate of acceptance in United States we will need to revamp our education system. We need to bring more exposure of different races into the schools of our children. We will never defeat the closed minds of the ignorant until we put those prejudices to the test of a person to person encounter. To say that we hate black people when we have never met black people and we're only going on what we see on TV, we are basing our prejudices on what other people want us to believe.If we are going to defeat discrimination and bring about cultural pluralism we will need to put those thoughts in the minds of our children. Education and first-hand experience is the only way they were going to bring about pluralism in the United States. There are too many rural communities where prejudices still exist today based upon ideals from 50 years ago. In what ways do the media perpetuate stereotyping and prejudice? Provide examples to support your assertion.

A Summary on the Article

The article entitled Omit the Unimportant discusses design in general and how it should be executed. There have been numerous technological innovations at this time and people patronize them because these things make their lives easier and more comfortable.However, many companies forget this important fact and turn their efforts to a product's design. They spend too much time on unnecessary details just to sell a product that they do not realize that the product has lost its functionality because of these details.â€Å"One of the most significant design principles is to omit the unimportant in order to emphasize the important† (Rams, 1989). Designers need to remember that simplicity can speak so much more than a complicated design.They need to go back to the basics and ask themselves what their customers want to see in them: functionality or design? While design is an important factor of a product, there is no doubt that their functionality should still be their main strength in terms of their ability to sell to the consumers.â€Å"Complicated, unnecessary forms are nothing more than designers' escapades that function as self-expression instead of expressing the product's functions† (Rams, 1989).It is also important for designers to remember that consumers are very influenced by a product's design. While this is beneficial for designers, it is not what consumers really need and they do not realize this soon enough.The author indicates two essential points that should be taken into consideration when designing. The first is that â€Å"items should be designed   in such a way that their function and attributes are directly understood† (Rams, 1989). Designers should be creative and innovative when it comes to their designs.However, their designs should not be misleading and confusing. They should remember that people appreciate it more when they can use something without too much effort. It all goes back to the basics: people patronize these innovations due to the way they make lives easier. Complicated designs and products loses this basic point.The second point that the author tries to make is that â€Å"the fewer the opportunities used to create informative designs, the more design serves to evoke emotional responses† (Rams, 1989).This means that people are influenced to buy a product just because of what it looks like. It also means that the more designers focus on the product's design, the more that the product's functionality is compromised. Products nowadays are made so as to attract people to be able to sell more.What the author suggests is for designers to go back to the idea of simplicity. Competition cannot be helped and it will always be present in all fields.However, this is not the only factor that makes a product â€Å"sellable† to consumers. No matter how great the design is if it proves to be confusing or not practical because the functionality is lost, the product will not sell in the ma rket. â€Å"Design is the effort to make products in such a way that they are useful to people† (Rams, 1989).Having said all these, it is still important to note that the author does not have anything against a great design. What he wants to say is that a product can have both without compromising the other.A product does not have to have a complicated design to be able to sell. In short, designers should omit those that are unnecessary so that they could focus more on the product's uses.Many people, especially those who belong in the older age groups, do not really mind how a product looks like as long as it does what it is supposed to do.

Children Act 1989 Essay Example | Topics and Well Written Essays - 1000 words

Children Act 1989 - Essay Example The Act emphasizes that, where possible, children should participate in decision-making about their future well being. Subject only to the child's understanding, such participation requires that a child is provided with relevant information and is consulted at every stage in the process of decision-making. It is the general duty of every Local Authority to: Safeguard and promote the welfare of children within their area who are in need and So far as is consistent with that duty, to promote the upbringing of such children by their families by providing a range and level of services appropriate to those children's needs and design it to help prevent abuse and neglect. The keynote to achieving this aim is careful joint planning and agreement in the provision of services within the family home, assisting and enhancing the parental authority. As per the Children Act relative to the Department of constitutional affairs, since the act and the strategies impact directly upon young people in their own right particularly in areas such as helping the vulnerable and increasing confidence in justice. They also influence the future habits of young people in areas such as proportionate dispute resolution and democratic engagement. As with other stakeholders the DCA benefits from gaining the views of young people on policy in these areas. In view of this, Learning to Listen states that in all government departments: A visible commitment is made to involving children and young people, underpinned by appropriate resources to build a capacity to implement policies of participation. And that The contributions of Children and young people, proportionate to their age and maturity, are taken seriously and acted upon, and feedback from children and young people confirm this.' Giving children and young people an active say in policies ensures that they genuinely meet their needs After all it is the child who will have to live with the outcome of the procedure. The Children Act 1989 states that children's wishes and feelings should be incorporated into the decision-making concerning them. Legally based intervention Children's act 1989 is fully equipped with the legal laws and norms that strengthen the cause of Child welfare. These legal intervention are mostly carried out in assistance of Local authority Duty to Investigate -

Microsoft To Issue Record Number of Patches Essay

Microsoft To Issue Record Number of Patches - Essay Example To find the average of values in B3 and B4, a formula = (B3+B4)/2 is typed into, say cell E2, giving the4 average. Entering a value into the cell causes the value to be visible in the formula thus enabling it to be changed without edition of the formula. The easiest way to enter cell references into formulas is by typing the reference. To use values in B4 and B6 in a formula meant to calculate monthly revenue, one types in = B4+B6 then enter to get a result. However, it is much easier to utilize functions, which are algorithms that can be followed, by excel, to attain a result (Smart 5). To get the average of values in B3 and B4, one could type = then type the average function’s name, followed by a left parenthesis, then the two cells. After typing a colon, excel discerns that one is defining a cell range. On entering the cell references, one types, a right parenthesis and then presses enter to get the result. Charts display a series of numeric data in the form of a graph in order to make it easier to understand enormous quantities of data, in addition to the relationships, between the data series (Smart 7). Excel supports many chart types that help one to display data in a meaningful manner. Charts have many elements with some displayed by default, and others added when needed. The display of the elements in the chart can be changed by moving them to different chart locations, adjusting their size or reformatting them. The spreadsheet consists of a chart area, plot area, plotted data points, category (horizontal) and value (vertical) axes, chart and axes titles, and data labels. After the creation of a chart, any of its elements can be modified. One can change the chart axes’ display, add data labels and titles, add a data table or legend, and apply a special option for every type of chart. To add a chart title, one click where the title is to be added, clicks chart title on the layout tab, clicks above chart, then types the

DIABETES - LITERATURE REVIEW Essay Example | Topics and Well Written Essays - 2500 words

DIABETES - LITERATURE REVIEW - Essay Example The objective was to analyse the risk factor index and the study concludes that the risk of diabetes is higher in Asians, Hispanics and blacks than whites before and after taking into account difference in BMI on the basis of the study evidences. The diatory and life style informations contributed to the data collection, the specific study methods verifies the dilatory intake in terms of caloric value as well as glycemic intake too. The data collection was done repeatedly for 4 years. Questionnaires were the assessment tool. Population:- Total population was 78419.Among these population the sampling done on the basis of ethnicity as Asians- 801, whites – 75,584, Hispanics-613 and black 1421. Inclusion criteria:- The inclusion criteria were considered only the selected population who have diabetes and who are willing to participate and the gender consideration was females. Exclusion Criteria:- Exclusion criteria include the diseases other than diabetes. Result:- The result says that â€Å"Compared with whites, the age-adjusted relative risks (RRs) were 1.43 (95% CI1.08–1.90) for Asians, 1.76 (1.32–2.34) for Hispanics, and 2.18 (1.82–2.61) for blacks. After adjustment for BMI, the RRs changed to 2.26 (1.70–2.99) for Asians, 1.86 (1.40–2.47) for Hispanics, and 1.34 (1.12–1.61) for blacks. ... A healthy diet high in cereal ?ber and polyunsaturated fat and low in transfat and glycemic load was more strongly associated with a lower risk of diabetes among minorities (RR 0.54 [95% CI 0.39–0.73]) than among whites (0.77 [0.72–0.84]). As Weight gain is particularly detrimental for Asians these data evidence towards the ethnicity along with diatory intake that the inverse association of a healthy diet with diabetes is stronger for minorities than for whites. Study evidences that the immigrated Asian women population have the high prevalence of diabetes and states that the diabetes and obesity are strongly associated each other along with the higher risk rate of cardio-vascular diseases incidence (Shai et al., 2006, p.1587). Article 2: ‘Prospective study of red meat consumption and type 2 diabetes in middle aged and elderly women by American Diabetes Association-2004’ The women heath study was conducted on the topic red meat consumption and association o f type 2 diabetes mellitus in middle aged and elderly women was done by the research team with the guidance of American diabetes association in 2004 ;leads to the evidences of diatory involvement in diabetes among the specified south Asian group. Study Design and Methods: Over an average of 8.8 years, evaluated 37,309 participants in the Women’s Health Study aged above 45 years who were free of cardiovascular disease, cancer, and type 2 diabetes and completed validated semi quantitative food frequency questionnaires in 1993. Questionnaire was the assessment tool. Participants: The study population contains 377,309 individuals. All participants were belongs to the female gender category. Inclusion criteria: The inclusion criterion includes

Tax Law in Qatar Research Paper Example | Topics and Well Written Essays - 750 words

Tax Law in Qatar - Research Paper Example The new Tax Law provided new views of the income. While the old system was more concerned with profits, the new law focused more on types and definition of income. According to the new law, gross income covers total income as well as profits from other sources. Additionally, the law indicates that the taxable income is arrived at by subtracting losses made from the past years from the net income. Other sources of income that the new law includes in the gross income includes income attained from the sale of shares, income from the sale of shares in Qatar companies, interest on the loan provided by Qatar banks, and income obtained from exploration services. The new tax law provided some notable exemptions. Qatari citizens who were not residing in Qatar were now eligible to pay tax on the income derived in Qatar. Residents of the Gulf Cooperation Council GCC States, as well as companies fully owned by GCC residents, are treated in the same way as Qatari companies and citizens as far as tax matters are concerned (Avi-Yonah and Slemrod, 2002). One of the key aspects of the new tax is that it still allowed the GCC companies and nationals to enjoy the same exemptions as Qatar citizens. The exemptions will have the impact on the GCC companies (Jeffs, 2008). For instance, a GCC firm that trades in Qatar but does not have a permanent location will be subjected to a specified withholding tax. One of the most notable changes in Qatar tax system was the tax rates. With the elimination of the marginal system that employed rates of 0 to 35%, the taxpayers now pay a flat rate of 10%. While large companies may welcome this strategy, it is may negatively affect the smaller taxpayers (Mohamed, 2014). For instance, in the old tax system, an individual with a taxable income of 400,000 QR would pay 10% on income ranging between 100,000 and 400,000 QR.

Healthcare Availability in the United States Essay

Healthcare Availability in the United States - Essay Example In the United States, there are three major types of healthcare insurances available to people which include Health Maintenance Organizations (HMO), Point-Of-Service Plans (POS), and Preferred Provider Organizations (PPO). HMO is a prepaid healthcare insurance plan in which a person just needs to pay a monthly premium to get a number of healthcare benefits. Some of the main benefits include emergency healthcare, laboratory tests, therapies, and free doctor visits. POS is an indemnity-type healthcare option for people in which they can go to doctors who are actually not in the network of doctors of the insurance plan. Patients can get health coverage even when they are referring to the doctors outside the plan. However, they need to pay coinsurance in such cases. Under this type of health coverage, a person does not need to pay monthly premium to get health benefits. Rather, he/she needs to show PPO card to the authorities to get the benefits in return of a small payment. In a PPO plan, a person can go to the doctors outside of the network but needs to pay a large portion of the total payment

Evaluation of Infection Control in Hospitals Essay

Evaluation of Infection Control in Hospitals - Essay Example The National Audit Office noted in its 2000 report that nine percent of all inpatients or one in every eleven inpatients in England had hospital acquired infection at any one time. This prevalence is higher than hospital acquired infections in Denmark (8%), Spain (8%), Netherlands (7%), Norway (7%) and Australia (6%). Only France (6-10%) and USA (5-10%) had higher incidence ranges (CPSO, 2004; Davis, 2005; POST, 2005). Furthermore, this figure is equivalent to approximately 100,000 hospital acquired infections per year. The effects of hospital acquired infections to patients range from minor discomfort to mortality in around 5,000 cases. These infections are considered as contributory factors to approximately 15,000 deaths a year (College of Nurses of Ontario, 2005; POST, 2005; Davis, 2005). A report by the Nosocomial Infection National Surveillance Service from 1997 to 1999, covering 96 hospitals in England showed 47 percent of microorganisms that cause surgical site infections were staphylococci. Eighty-one percent of these were Staphylococcus aureus and 61 percent were Methicillin Resistant Staphylococcus Aureus (MRSA) (CPSO, 2004; Davis, 2005; POST, 2005). All of these occurrences are attributed to o... In order to know the root of the problem which is the declining level of hygiene in hospitals, the sources and possible routes of infectious materials should be identified. Gaps and loopholes for the proper handling of such infection sources and vectors should be highlighted. Next, appropriate steps should be put in place that will answer these inefficiencies together with the responsible hospital staff for each task. Lastly, monitoring and maintenance systems should be developed to ensure long-term success in these efforts with emphasis on in any areas where improvements are needed (College of Nurses of Ontario, 2005; POST, 2005; Davis, 2005). Studies and information already available for the abovementioned factors will be reiterated here. However, this paper will focus on other areas where data are lacking and further research is warranted. More specifically, the role of social workers in the proliferation and solution of hospital acquired infections will be assessed. Furthermore, research gaps in this area will be identified towards the development of qualitative and quantitative research methodologies. Epidemiology of Hospital Acquired Infections Hospital acquired infections are also referred to as nosocomial infections. These are infections that develop during the patient's stay in the hospital that were not previously present. There are two types of hospital acquired infections: autoinfection wherein the causative agent is inherently present in the patient but started to proliferate during confinement because of lowered resistance level, and cross-contamination wherein the causative agent comes from outside the patient which infects and develop during the patient's stay in the hospital (CPSO, 2004; Davis,

De Havilland Vehicles Essay Example | Topics and Well Written Essays - 3000 words

De Havilland Vehicles - Essay Example The sales office has on-line access to the manufacturer's vehicle tracking system to establish the availability of cars by model, colour and extras. Cars can be ordered directly, but there is no internal system to store data on products or customers, only a card index system. DHV plc also uses paper-based systems to administrate its service and repair booking system, job cards, supplier data, orders, personnel and training. DHV plc has three distinct parts to its business. They act as a middleman for a car manufacturer selling their new vehicles. Last year (2004) 50% of their car sales were new split 40% to business and 10% to private users. The new car warranties and used vehicle guarantees tie customers in for subsequent servicing which builds long term relationships. The company seeks to retain these customers when the warranty or guarantee expires. The company also has a buoyant local repair trade. Whilst the directors of DHV plc have determined that e-Business and more integrated Information Systems is the appropriate way forward to achieve their new objectives it might help define the detail of the problem more accurately by researching not only what the competition are doing but also what e-Business innovations other distribution companies of high value items are usi... Cars can be ordered directly, but there is no internal system to store data on products or customers, only a card index system. DHV plc also uses paper-based systems to administrate its service and repair booking system, job cards, supplier data, orders, personnel and training. 2.2 Market Information DHV plc has three distinct parts to its business. They act as a middleman for a car manufacturer selling their new vehicles. Last year (2004) 50% of their car sales were new split 40% to business and 10% to private users. The other 50% of their car sales were used vehicles and they include guarantees with all second-hand cars sold. The new car warranties and used vehicle guarantees tie customers in for subsequent servicing which builds long term relationships. The company seeks to retain these customers when the warranty or guarantee expires. The company also has a buoyant local repair trade. 3. e-Business Problem Definition and Objectives Whilst the directors of DHV plc have determined that e-Business and more integrated Information Systems is the appropriate way forward to achieve their new objectives it might help define the detail of the problem more accurately by researching not only what the competition are doing but also what e-Business innovations other distribution companies of high value items are using. It might help reinforce the soundness of their strategy and point them in the right direction. 3.1 E-Business ideas for DHV plc According to Lou Gerstner, (CEO IBM 1993-2002): The internet is increasingly playing a more strategic role in business processes and failure to recognise this and take advantage of its potential could result in an organisation being left behind in todays over competitive environment.(Source, Internet & Business,

Combating compassion fatigue Assignment Example | Topics and Well Written Essays - 1250 words

Combating compassion fatigue - Assignment Example This eventually takes compassion and attention away from victims to the caregiver himself. Essentially, fatigue sets in for the provision of care; thereby jeopardizing the need to give compassion to victims. The cause of depression in caregivers that results in compassion fatigue could best be associated with excessive work that is deprived of rest (Ellard, Barlow and Mian, 2005). Anger Quick temperedness and erupted outburst of anger that is so sudden and uncharacteristic of a caregiver must be seen as a major sign that compassion fatigue is setting into the work and activity of the caregiver. As a care giver, come of the core duties that will generally be expected is the need to give compassion and solace to a heart that is deeply troubled and as such filled with so much inner anger (Day and Livingstone, 2003). When there is anger on the side of the caregiver then, this basic responsibility becomes jeopardized and compromised because it cannot be executed evenly. Once a caregiver b egins to be angry at the least provocation, the tendency is that the victim who decides care would even be angered at and so the level of compassion will be derailed. Such acts of anger are mostly caused by emotional factors that have to do with issues faced in the personal lives of caregivers (Forsythe and Compas, 1987). Absent mindedness Victims who go to the caregiver go to them with a thought that the caregiver is going to be an expert and a professional who is going to bare all the troubles that the victim brings on board. For this reason, it is always going to be expected that the victim would demand for constant attention from the caregiver. For this reason, caregivers who begin to have signs of absent mindedness when attending to victims and other people who are close to them must be aware of the possibility of compassion fatigue setting in. clearly, the caregiver would be absent minded because he or she has had a reduced degree of importance to the issue or case of the vict im and this is what compassion fatigue is all about (Albino et al., 2003). Taking too much work than a caregiver can genuinely deliver is a major cause of absent mindedness; especially when tiredness sets in. Sluggishness In the everyday delivery of their duties, caregivers are expected to be very sharp at what they do. Such acts of sharpness install a lot of confidence in victims. It also increases the trust that they have in caregivers. For this reason, any acts of laziness and sluggishness should be watched critically and be seen as a possible cause of the onset of compassion fatigue. Indeed, if there is no strength to carry out one’s duties and so the person begins to show signs of sluggishness at work, there is no way that person will be expected to deliver the same level or amount of compassion that he or she delivered to victims. Sluggishness is a direct reflection of tiredness and so tiredness and lack of rest could cause it. Stress Psychologists and other social comm entators have attributed stress to be a very emotional and psychological problem that comes with a tired mind. The mind as an organ in the body has its own roles and functions that it plays. Though it is known that the mind controls most activities and functions of the body, the mind also has its own limitations (Cortoni and Marshall, 2001). The mind cannot for instance be expected to be omniscient, knowing all things and doing everything at every

Importance of International Trade Essay Example for Free

Importance of International Trade Essay The buying and selling of goods and services across national borders is known as international trade. International trade is the backbone of our modern, commercial world, as producers in various nations try to profit from an expanded market, rather than be limited to selling within their own borders. There are many reasons that trade across national borders occurs, including lower production costs in one region versus another, specialized industries, lack or surplus of natural resources and consumer tastes. One of the most controversial components of international trade today is the lower production costs of developing nations. There is currently a great deal of concern over jobs being taken away from the United States, member countries of the European Union and other developed nations as countries such as China, Korea, India, Indonesia and others produce goods and services at much lower costs. Both the United States and the European Union have imposed severe restrictions on imports from Asian nations to try to stem this tide. Clearly, a company that can pay its workers the equivalent of dollars a day, as compared to dollars an hour, has a distinct selling advantage. Nevertheless, American and European consumers are only too happy to lower their costs of living by taking advantage of cheaper, imported goods. Even though many consumers prefer to buy less expensive goods, some international trade is fostered by a specialized industry that has developed due to national talent and/or tradition. Swiss watches, for example, will never be price-competitive with mass produced watches from Asia. Regardless, there is a strong market among certain consumer groups for the quality, endurance and even snob appeal that owning a Rolex, Patek-Philippe or Audemars Piguet offers. German cutlery, English bone China, Scottish wool, fine French silks such as Hermes and other such products always find their way onto the international trade scene because consumers in many parts of the world are willing to foster the importation o f these goods to satisfy their concept that certain countries are the best at making certain goods. One of the biggest components of international trade, both in terms of volume and value of goods is oil. Total net oil imports in 2005 are over 26 million barrels per day (U.S. Energy Information Administration figures) (Note: Imports include crude oil, natural gas liquids, and refined products.) At a recent  average of $50 per barrel, that translates to $1billion, three hundred million, PER DAY. The natural resources of a handful of nations, most notably the nations of OPEC, the Organization of Petroleum Exporting Countries, are swept onto the international trade scene in staggering numbers each day, and consumer nations continue to absorb this flow. Other natural resources contribute to the movement of international trade, but none to the extent of the oil trade. Diamonds from Africa, both for industrial and jewelry use, wheat and other agricultural products from the United States and Australia, coal and steel from Canada and Russia, all flow across borders from these nations that have the natural resources to the nations that lack them. Despite complaints about trade imbalances, effects on domestic economies, currency upheavals, and loss of jobs, the reality of goods and services continually crossing borders will not go away. International trade will continue to be the engine that runs most nations. Information is for educational and informational purposes only and is not be interpreted as financial advice. This does not represent a recommendation to buy, sell, or hold any security. Please consult your financial advisor.

Bilingual Acquisition in Early Childhood

Bilingual Acquisition in Early Childhood Are bilingual children two monolingual children in one? Discuss. Research into bilingual acquisition in early childhood has investigated whether infants and toddlers brought up in bilingual settings can be said to have a single language system during the initial stages of language acquisition or whether these early bilinguals develop two separate language systems from the start. If the latter can be shown to be the case, it could be argued that bilingual children are indeed two monolingual children in one. However, there has been considerable debate over the merits of both claims for some period of time. This essay will consider the arguments and some of the evidence put forward in support of both points of view. Researchers differentiate between two languages acquired from birth (simultaneous bilingual acquisition) and the acquisition of a second language during early childhood. Research, intending to address the question of developing bilingual language systems in the infant, focuses on simultaneous bilingual acquisition. Although as Lanza points out it isn’t always easy to decide on â€Å"the cut-off point between first language acquisition and early second-language acquisition.† [1] The language environment, with both parents speaking both languages or the adoption of a one language one parent approach, is also a consideration. It is often pointed out that bilingual children acquire their languages in much the same way as monolingual children acquire theirs. Pearson and colleagues testing the acquisition of vocabulary found that â€Å"differences in average vocabulary size (between the bilingual and monolingual children in their study) across the age range tested were relat ively small.†[2] Studies of childhood bilingual development have shown that in almost all cases, children mix elements from the two languages they are acquiring. This has lead to claims that in the early stages of acquisition bilingual children have a single language system. Code mixing may involve any aspect of the child’s language system i.e., phonetic, lexical, phrasal, syntactic, semantic and pragmatic. Code mixing is not limited to children. Many researchers have investigated the phenomenon of code mixing or switching in adult bilinguals. However, there are important differences between the two. Adult code switching is rule governed. â€Å"What is thought to distinguish bilingual children’s mixing from adult mixing is the lack of systematicity or compliance to linguistic rules in the case of children.† [3] The fact that mixing declines with age has been cited as evidence that the child originally had one system that gradually separates into two. The period of mixing is followed by language differentiation sometime during the bilingual child’s third year. Volterra and Taeschner’s seminal paper interpreting code mixing in terms of a three-stage model of a single language system has had numerous supporters and critics. [4] A growing number of researchers have published papers in the past couple of decades supporting a two-language system. In 1985 Vihman looked at a bilingual Estonian/ English child. Having pointed out that there was insufficient data concerning the child’s comprehension skills in both languages to confirm whether or not he had a single system: â€Å"It seems likely that two receptive stores did exist in a rudimentary form even at this earliest stage, however, since comprehension appeared to develop rapidly in both English and Estonian contexts well before the development of a wide-ranging productive vocabulary.† [5] Considerable research has shown that monolingual children develop comprehension before production skills. The author agreed with Lindholm and Padilla[6] that â€Å"bilingual children are able, from an early age, to differentiate their two systems†. [7] Genesee also found evidence of â€Å"differentiated underlying language systems† in his study of early bilinguals. He argued that â€Å"bilingual children are able to differentiate their language systems from the beginning and that they are able to use their developing language systems differentially in contextually sensitive ways.† [8] Paradis and Genesee concluded the bilingual children in their study developed entirely distinct pronoun system for the two languages. [9]Their research therefore supports the separate language hypothesis. Likewise, Quay’s study of an English/ Spanish bilingual child â€Å"provides no evidence for the two-stage model of lexical development proposed by Volterra and Taeschner.† [10] Empirical and Interpretative Difficulties Methodology Most researchers criticise the methodology used by previous researchers in the field. Diary studies of a single child are common making any generalisation difficult. Other factors making comparison and therefore generalisation difficult include: the differing exposure to the languages experienced by each child, their different language backgrounds and history, the different methods of language sampling undertaken by the various researchers, and the fact that to date there is no standardised measurements to compare children at various stages of bilingual development. Furthermore, diary studies may be insufficient to accurately reflect the linguistic competence of the child studied, regardless of whether or not the findings can be shown to be valid for other bilinguals. â€Å"Diary data may not capture all translation equivalents.† [11] Quay also points out that studies making use of audio and video recordings tend not to make them frequently enough: â€Å"Infrequent recordings for a short duration each time do not allow for conclusive evidence with regard to bilingual children’s ability to produce translation equivalents.†[12] Radford reviewing Paradis and Genesee (1996) remarks on a methodological shortcoming noted in many other studies, the use of a small corpus of data: â€Å"This might lead us to the conclusion that PG simply didn’t have enough data from enough children to support the sweeping theoretical claims that they make.†[13] Pearson and colleagues also criticize the emphasis on case studies â€Å"a form in which systematic comparisons with other children are not generally attempted.† [14] Their own research compared the language development of 25 English/ Spanish bilinguals with 35 monolinguals: â€Å"Without detailed information from a wide range of children, it is difficult to gain a broad perspective on what is typical and what is exceptional in early bilingual development.†[15] Radford states, â€Å"much of the evidence VT (Volterra and Taeschner) bring to bear in support of their claim that children start out with a common syntax for their two languages is based to a large extent on code-mixing.†[16] He suggests the fact that bilingual children are known to code mix cannot be seen as evidence for a single language system because adult also code switch and they are â€Å"generally assumed to have separate grammars for each language.† However, as has been stated earlier, children do not code mix in the way adults do. More problematic for supporters of the single language system is the finding by Genesee and colleagues that code mixing in early bilinguals is not as common as Volterra and Taeschner claim.[17] These researchers discovered that code mixing takes place in only 1%-7% of bilingual children’s utterances. Like Radford, Genesee claims that there are serious methodological and interpretative shortcomings with much research into simultaneous bilingualism. In order for the single system hypothesis to be valid, bilingual children would need to â€Å"use items from both languages indiscriminately in all contexts of communication.†[18] However, as Genesee makes clear, most research in the field has failed to analyse the data by context. Volterra and Taeschner for example, present isolated examples of the child addressing one parent only.[19] Vihman did look at her bilingual child’s utterances in context but she focused on one language only.[20] If the appearance, then decline, of code mixing in early bilingual development is not necessarily evidence of a single language system, what other factors may be responsible for the phenomenon? Vihman (1985) argues that the decline in mixing has more to do with the bilingual child gaining in sociolinguistic competence than evidence of the separation of language systems.[21] Lanza also suggests a more sociolinguistic explanation for code mixing: â€Å"Children do learn to differentiate their language: however, this differentiation process occurs in language socialisation through which they learn to differentiate ways of speaking according to the social demands of the situation.† [22] Other researchers point out that with the acquisition of more lexical items as the child’s language skills develop, there is less need to borrow between languages (the lexical gap hypothesis).[23] [24] Peterson claims bilingual children switch to their dominant language because they haven’t the lexicon or syntactic structure in the weaker one.[25] Bernardini agrees â€Å" in some young bilingual children†¦with uneven development, having one language that is clearly weaker than the other, sentence-internal code-mixing is a result of uneven lexical development in the two languages.† [26] Pearson and colleagues test the Volterra Taeschner (1978) claim â€Å"if children already have a lexical representation for a concept in either language, they will not be motivated to learn or use the word’s translation in the other.†[27] This follows Clark’s principle of contrast, which predicts an absence of synonymy in early lexical development in both monolingual and bilingual children.[28] Pearson and colleagues found no evidence to support Volterra Taeschner in their study of 27 early bilinguals. Quay also found â€Å"no foundation for the principle of contrast in (the) bilingual case (studied).† Quay points out â€Å"most studies do not take into account whether young bilinguals have the lexical resources to make a choice between their two languages.† [29] According to Grosjean one language may be dominant because the child is exposed to that language more frequently and needs it to communicate with more people.[30] Serratrice defined â€Å"language dominance in terms of the amount of input the child receives†. [31]It has been pointed out by a number of researchers that mixing may be linked to the child’s speech environment. [32] The bilingual child might code mix because he hears his parents or other adults doing so. It has been argued the â€Å"best way to avoid bilingual mixing in children is to have each parent speak only one language to the child.† [33] Quay suggests, â€Å"linguistic input from adult interlocutors must be taken into account in discussions of children’s language choices.†[34] Conclusions It is clear that many factors are involved in simultaneous bilingual acquisition. The debate over whether these young children develop one or two language systems initially has yet to be satisfactorily resolved. As many researchers point out parental input may well prove to be of particular importance. Whether the child has one system or two and thus resembles a single monolingual child or two monolingual children, it is clear that their â€Å"ability to understand two languages may be comparable in each language to monolingual children’s.†[35] Bernardini, P and Schlyter, S (2004) Growing syntactic structure and code-mixing in the weaker language: The Ivy hypothesis. Bilingualism: Language and Cognition 7, 49-70 Clark, E (1987) The principle of contrast: a constraint on language acquisition. In B. MacWhinney (ed.) Mechanisms of Language Acquisition. Hillsdale, NJ: Erlbaum. Genesee, F (1989) Early bilingual development: one language or two? Journal of Child Language 16, 161-179 Genesee, F. Nicoladis, E Paradis, J (1995) Language differentiation in early bilingual development. Journal of Child language 22, 611-630 Grosjean, F (1982) Life with two languages: an introduction to bilingualism. Cambridge MA: Harvard Uni press Lanza, E. (1992) Can bilingual two-year-olds code-switch? Journal of Child language 19, 633-657 Lindholm, K and Padilla, A (1978) Child bilingualism: report on language mixing, switching and translations. Linguistics 211, 23-44 Paradis, J. and Genesee, F. (1996). ‘Syntactic acquisition in bilingual children: autonomous orinterdependent?’ Studies in Second Language Acquisition 18: 1-25. Pearson, B, Fernandez, S and Oller, D 1993. Lexical development in bilingual infants and toddlers: comparison to Monolingual norms. Language Learning 43:1, 93-120 Pearson, B, Fernandez, S and Oller, D 1995. Cross-language synonyms in the lexicons of bilingual infants: One language or two? Journal of Child Language 22, 345-368 Pearson, B. Fernandez, S. Lewedeg, V Oller, K (1997). The relation of input factors to lexical learning by bilingual infants. Applied Psycholinguistics 18, 41-58 Peterson, J (1988) Word-internal code-switching constraints in a bilingual child’s grammar. Linguistics, 26, 479-493 Quay, S (1995) The bilingual lexicon: implications for studies of language choice. Journal of Child Language 22, 369-387 Radford, A (2005) Children’s English: Principles-and-Parameters Perspectives. University of Essex. Serratrice, L. Referential cohesion in the narratives of bilingual English-Italian children and monolingual peers. Journal of Pragmatics 39 (2007) 1058–1087 1083 Vihman, M. (1985) Language differentiation by the bilingual infant. Journal of Child Language 12, 297-324 Volterra, T and Taeschner, T (1978) The acquisition and development of language by bilingual children. Journal of Child Language 5, 311-326 1 Footnotes [1] Lanza (1992:634) [2] Pearson et al (1993:112) [3] Genesee (1989) [4] Volterra and Taeschner (1978) [5] Vihman (1985:316) [6] Lindholm and Padilla (1978) [7] Vihman (1985:317) [8] Genesee (1989:174) [9] Paradis and Genesee (1996). [10] Quay (1995:385) [11] Quay (1995:382) [12] Quay (1995:383) [13] Radford (2005) [14] Pearson et al (1993:95) [15] Pearson et al (1995:348) [16] Radford (2005) [17] Genesee et al (1995) [18] Genesee (1989:165) [19] Volterra and Taeschner (1978) [20] Vihman (1985) [21] Vihman (1985) [22] Lanza (1992:654) [23] Volterra and Taeschner (1978) [24] Lindholm and Padilla (1978) [25] Peterson (1988) [26] Bernardini and Schlyter (2004:49) [27] Pearson et al (1995:346) [28] Clark (1987) [29] Quay (1995:369) [30] Grosjean (1982) [31] Serratrice (2007) [32] Genesee (1989) [33] Genesee (1989:170) [34] Quay (1995:383) [35] Pearson et al (1993:113)

Chemistry of All-carbon Materials: Structure and Properties

Chemistry of All-carbon Materials: Structure and Properties All-carbon materials have received lots of attention in the past. Carbyne, a new allotrope of carbon, is still in controversy towards its synthesis and property. Combining with the Goroff group’s research, this project is to prepare the polymer PIDA (polydiiododiacetylene) as a polyrotaxane complex, encapsulated in a column of macrocyclic hosts. The polyrotaxane structure will prevent aggregation of the PIDA strands, allowing for the complete dehalogenation of the polymer to make carbyne. The proposed route is shown in Scheme 1.1. PIDA, a precursor of carbyne, can be made from diiodobutadiyne and macrocyclic hosts via topochemical polymerization and host-guest strategy, in which macrocyclic host will self-assemble into column structure and diiodobutadiyne will form halogen bonds with host. All-carbon materials have been widely investigated because of their potential properties, such as electrical conductivity, thermal conductivity and hardness. They exist in different morphologies with various properties, such as diamond, graphite, carbon nanotube, graphere, fullerene and carbyne . Diamond, consisting of all sp3 hybridized carbons, has many unusual properties, such as extreme hardness, high optical transmittance and wide band gap and so on.1 Because of these potential properties, the synthesis of diamond is of great interest. It can be synthesized through chemical vapor deposition, including hot filament chemical vapor deposition (HFCVD); high frequency plasma-assisted chemical vapor deposition (PACVD); and DC plasma discharge.1b Graphite is made of sp2 hybridized carbon. It has a layered honeycomb structure and behaves as a good conductor.2 Fullerenes exist in different sizes, such as C60, C70 and C82. The C60 fullerene was first reported by Kroto and coworkers.3 It is an all-carbon polyhedral cage molecule with each atom sp2 hybridized and directly bonded to three neighbors. All valences of carbon atom in the molecule are satisfied by two single bonds and one double bond. Graphene is single atom thick layer of graphite, which can be used in composite material , electric battery and hydrogen storage.4 Carbon nanotubes usually have cylindrical nanostructure and made of different length-to-diameter ratio. Because of its special electrical, electrochemical and optical properties, carbon nanotubes were widely investigated in electronics, biological and energy application.5 Carbyne, having all-sp-hybridized carbon, is highly reactive. Carbyne, an sp hybridized all-carbon chain, is a new allotrope of carbon and has potential special properties as all carbon material, which has attracted considerable interest since discovery back in 1960. Because of its instability, it is less well known than the other carbon allotropes. The investigation of carbyne or carbyne-like structures is still underway while the results are often unclear. Researchers have tried to synthesize carbyne or carbyne-like materials in several ways, such as chemical dehydrohalogenation and electrochemical synthesis. Evsyukov et al.6 studied dehydrohalogenation of poly (ethylene-alt-chlorotrifluoroethylene)(PE-a-CTFE)to make carbyne. PE-a-CTFE was treated with potassium tert-butoxide in tetrahydrofuran to form a halogen-substituted polyenyne structure with randomly distributed isolated triple bonds. Theoretically, the synthesis was showed below. Elimination of hydrogen halides was incomplete, which could result from the insufficient strength of the base, sterical hindrances caused by its bulkiness and alternation defects in the original copolymer. Wang and coworkers7 claimed to form carbyne-like material via electrochemical method. 1, 1, 2-trichloroethylene was dehydrochlorinated with t-buthanolate, which was formed from t-butylalcohol on a Ni cathode in dimethylsulfoxide electrolyte solution under anaerobic conditions. However, this method was not effective because of reactive carbon, oxidation with O2 and cross-linking of polyyne-like chains. In above reports, no evidence of formation of carbyne is observed and the properties of carbyne remain unrealized. Recently, polyynes, analogues of carbyne, have been widely investigated to predict the properties of carbyne. Polyynes are one-dimensional chains with alternating single and triple bonds. The synthesis of long polyynes chains was first reported by Walton and coworkers.8 They used Cu-catalyzed oxidative Hay coupling techniques to synthesize triethylsilyl-capped polyynes. Tykwinski and coworkers also synthesized several polyynes with a variety of end groups, in which bulky end groups would increase the stability and solubility of polyynes. In 2010, Tykwinski reported the synthesis of polyynes with as manys as 44 sp-carbons.9 They used bulky tris(3,5-di-t-butylphenyl)methyl (Tr) as end groups and stabilize the chain. The synthesis method is shown in Scheme 1.4. When the polyynes become larger and larger, the effect on stability of end groups becomes insufficient. In order to overcome this issue, some researchers encapsulated polyynes into macrocycles to form rotaxanes or polyrotaxanes. Sugiyama and coworkers10 prepared pseudo-rotaxanes and rotaxanes with cyclodextrin simultaneously to stabilize and to solubilize the carbyne chains. Tykwinski and coworkers11 synthesized polyyne rotaxanes with 4, 6 and 10 triple bonds in length through active copper-templated coupling. Inspired by these cases, I am trying to design a polyrotaxane, allowing for complete dehalogenation of PIDA to make carbyne. Polydiacetylenes (PDAs), conjugated polymers with alternating double and triple bonds in the backbone, are prepared via topochemical polymerization of aligned diynes. Generally, topochemical polymerizations occur in a condensed phase, in which the monomers are preorganized and the final structures of the product are determined by the preorganization. In 1969, the synthesis of PDA was first described by Wegner,12 introducing the 1, 4-polymization of monomers. In addition, Baughman demonstrated how 1, 4-polymerization of diynes works and reported necessary parameters for the 1, 4-polymerization.13 The monomers are held in alignment. The distance between adjacent monomers is near 5 Ã…. The intermolecular distance of reacting carbons (C4 and C1’) is close to 3.5 Ã…, which is close to the van der Waals radius of carbon. The tilt angle between monomer diyne and the vertical translation axis should be 45 °. Ideal 1, 4-polymerization of diynes is showed below. Host-guest strategy is used to describe how monomers are aligned for polymerization. Different molecules or ions are held together by some forces to form complexes. In order for topochemical polymerization, monomers should be aligned to meet the geometric requirements. However, some monomers cannot form the right geometry required to polymerize. Host-guest strategy is applied to adjust the monomers to meet the requirements reported by Baughman. Here, hydrogen bonding and halogen bonding work in 1, 4-polymerization through host-guest strategy. Recently, Fowler and Lauher developed different kinds of diyne monomers to undergo 1, 4-polymerization using the host-guest strategy. In this way, the diyne monomers played the role of guests, which then formed hydrogen bonds with host molecules. The host molecules possessing oxalamides and ureas self-assembled into a structure via hydrogen bonding. Because of hydrogen bonding interactions, the diyne monomers were aligned in proper geometry for 1, 4-polymerization. The following is an example of host-gust strategy for one diyne.14 In the cocrystals, the oxalamide host molecule was organized through hydrogen bond with a repeat distance of 4.97 Ã…. The nicotinyl ester groups of the diyne guest monomers form strong pyridine-carboxylic acid hydrogen bonds to the host molecules. In addition to Fowler and Lauher’ work, the Goroff group also showed halogen bonding interaction could be applied for 1, 4-polymerization with the host-guest strategy. sp2 and sp hybridized carbon is more electronegative than iodine. Iodoalkynes behaves as Lewis acids and form halogen bonds with Lewis bases, such as pyridine and nitriles. The following is an example of host-gust strategy for diiodobutadiyne (figure 1.3).15 In this case, diiodobutadiyne played the role of guest. The hosts with oxalamide group were also organized through hydrogen bonds and designed to align diiodobutadiyne in the right geometry for 1, 4-topochemcal polymerization. The repeat distance of diyne monomers was 5.11 Ã…. The tilt angle was 51 °. Halogen bonds (XBs) is a non-covalent interaction which consists of halogen atom and other neutral atom or anions. The general structure of halogen bonds is showed in Figure 1.4.16 In this structure, X is halogen atom, which accepts electron density. It can be Lewis acid and halogen bond donor. D is the one donate electron density, which behaves as Lewis base and halogen bond acceptor. Y is a carbon, nitrogen, or halogen atom. The investigation of XB has been continuing for near 200 years. In 1863, the first report on the ability of halogen atoms to form well-defined adducts with electron donor species was described by Frederick Guthrie.17 In his experiment, I2 was added to saturated ammonium salt (nitrate or carbonate) and a diiodine/ ammonia system NH3†¢I2 formed. After exposed to air, it decomposes spontaneously into ammonia and iodine, without permanent gas being evolved. After that, halogen bonds became widely investigated. H. A. Benesi and J. H. Hildebrand identified the iodine-benzene complexe through UV-vis spectra in 1948.18 In 1954, Hassel’s group used X-ray to show the structure of bromine 1, 4-dioxanate.19 The experiment showed there was a short intermolecular interaction between the oxygen atoms of dioxane and bromine atoms. The interaction was halogen bond. The distance of O−Br bond was just 2.71 Ã…, which indicated a strong interaction between the bromine and oxygen atom s. Pierangleo Metrangolo and Guiseppe Resnati, whose research focused on halogen bonds, summarized the characteristic of halogen bonds and their interaction.16, 20 Polarizability increases when you move down the periodic table from fluorine atom to the iodine atom. This makes Cl, Br and I have the positive potential charge, which is showed in Figure 1.5. When the halogen atom is attached to an electron-withdrawing group, the positively polarized area will increase. On the one hand, the halogen atom can be the acceptor of electron density. On the other hand, the positive charge locates at sphere’s end, which is surrounded by electron neutral ring and negative charge belt. Because of the special location of positive charge, the angle of covalent bond and noncovalent bond around halogen atom in D†¢Ã¢â‚¬ ¢Ã¢â‚¬ ¢Ã¢â‚¬ ¢X—Y is near 180 °. This is consistent with research results. Hongjian Jin et al.21 used diiodobutadiyne and bis(pyridyl)oxalamides to make cocrystal, whi ch was based on halogen bonds between pyridine group’s nitrogen and iodine. Polymerization of cocrystal was induced under 3.5 GPa pressure. Although the N†¢Ã¢â‚¬ ¢Ã¢â‚¬ ¢Ã¢â‚¬ ¢I—C angle changed after polymerization, both angles were still near 180 °. They were 169.7 ° and 161.4 °. Investigation of halogen bonds examples in the Cambridge Structure Database is also shown. Metrangolo and Resnati16, 20 showed that halogen bond was relative stronger than hydrogen bond. However, a halogen is larger and more polarizable than hydrogen and halogen bonds are more sensitive to steric hindrance than hydrogen bonds. Halogen atom, electron acceptor in XBs, has some general characteristics. Among the four halogen atoms, the order for forming strong halogen bonding is I >Br > Cl >F. The more electron withdrawing atom is, the stronger is the halogen bonds. As to halocarbons, the strength order for halogen bonding is C-X (sp)>C-X (sp2)> C-X (sp3). If the halocarbons are unfunctionalized monohaloalkanes, no halogen bonds are observed. Diiodobutadiyne, in which the C is sp hybridized, is a good Lewis acid.22 The Goroff group used diiodobutadiyne as a guest to make poly (diiododiacetylene) (PIDA) with several hosts. Self-assembly of macrocycles Supramolecular chemistry is a rapidly growing field, emphasizing on assembly of discrete molecules. Traditional chemistry deals with covalent interaction while supramolecular chemistry focuses more on noncovalent interactions, such as hydrogen bonding23, van der Waals forces24 and Ï€-Ï€ interactions25. Self-assembly, a main process involved in supramolecular chemistry, will take advantage of these noncovalent interactions to organize discrete molecules into high order structures. Macrocycles, which have cyclic structures with other functional groups, can be self-assembled in a specific manner to form high order structures. Here I will introduce the self-assembly of macrocycles through hydrogen bonding and Ï€-Ï€ interactions. Ï€-Ï€ interactions, well known noncovalent intermolecular interactions, play important roles in self-assembly of macrocycles. The arrangement of aromatic rings has following geometries, such as face-to-face, edge-to-face and slipped stack. Hill and coworkers26 synthesized amphiphilic hexa-peri-hexabenzocoronene, self-assembling via Ï€-Ï€ stacking to form a discrete nanotubular object. The object has a uniform and 14-nanometer-wide hollow space. Lauher and coworkers27 also took advantage of Ï€-Ï€ stacking to design a tubular macrocyclic polymer. The monomer structure and route to a tubular polymer are shown in Figure 1.7. The diacetylene-based macrocycles self-assembled into polymerizable slipped Ï€-Ï€ stack and polymerized via slow annealing. The macrocycle had two different crystalline forms, which were monoclinic and triclinic form, respectively. After slow annealing at 40 à ¢Ã¢â‚¬Å¾Ã†â€™, the triclinic forms appeared to undergo crystal-to-crystal polymeriz ation. Hydrogen bond is an attraction force involves a hydrogen and strong electronegative atom, such as oxygen, nitrogen and fluorine. The electronegative atoms behave as hydrogen bond acceptor and hydrogen is hydrogen bond donor.28 Macrocyclic peptides and ureas can form high order tubular structures via hydrogen bonds. Ghadiri and coworkers29 used cyclo[-(L-Gln-D-Ala-L-Glu-D-Ala)2-] to self-assemble into hollow tubes via amide hydrogen bonds. Shimizu and coworkers30 also took advantage of amide hydrogen bond to organize diacetylene macrocycles for topochemical polymerization. In addition, Shimizu and coworkers used macrocyclic bis-ureas to self-assemble into columnar structures through urea hydrogen bonds. In the structure of macrocyclic bis-ureas, two hydrogen atoms in NH group are hydrogen bond donors and the carbonyl groups are hydrogen bond acceptors. The structures of the macrocyclic ureas are shown in figure 1.8. In 2001, they used bis-urea macrocycles with m-xylene to form the sel f-assembly tubular structures.31 The m-xylene kept the macrocycles rigid. However, this macrocycle formed intramolecular hydrogen bonds. Another bis-urea macrocycle with m-phenylether avoided forming intramolecular hydrogen bonds and organized into tubular structures with ordered acetic acid dimer filling inside as guest. The columns were stabilized by hydrogen bonding as well as Ï€-Ï€ staking interactions of phenylether. Except ureas, oxalamides are also used to form hydrogen bonding networks (figure 1.8). The repeat distances are 4.6 Ã… and 5.0 Ã…, respectively.33 Inspired by above work, we plan to design a macrocycle with pyridine, alkyne and oxalamide segments. Pyridine and alkyne segments provide beneficial rigidity, helping the macrocycles cocrystalize with diiodobutadiyne through halogen bonds. oxalamide segments are used for forming hydrogen bonding networks.

The Effects of Alcohol Essay -- Papers Alcohol Drinking Liquor Essays

The Effects of Alcohol Works Cited Not Included Alcohol is a substance that has numerous diverse affects on the body-both positive and negative. Alcohol not only kills brain cells, but when taken in profusion it has almost no constructive affects. Sure it can make one overlook his/her problems, but the consequences of drinking in excess far outweigh the benefits. It is not a crime to get drunk, however alcohol will almost always cause one to conduct them self in a way he or she would not normally behave. For instance, a sober man will not usually drive ninety-five mph down I-95, however, after consuming a good amount of alcohol, his eyesight, judgement, reflexes and abilities are hindered to the point that he feels indestructible. Alcohol is a drug, and when abused it has almost no positive affects. It is the most widely used and socially acceptable drug in the world. (Taylor, 6-7) Alcohol abuse is more physically destructive than the abuse of any other popular drug. When much is consumed in a short period of time, alcohol (ethanol) causes immediate changes in the body. First it slows down the workings of the brain. The drinker?s speech may become slurred and his steps staggered. The body?s reflexes become dulled as the nervous system slows down. (Taylor, 14) The drinker does not always realize this and may feel as if he is perfectly capable of normal functioning, but this is not always so. His abilities are impaired and he should not be given responsibility. Alcohol is often incorporated in many different aspects in our society. It is drunk as part of social celebrations such as birthdays, weddings, and parties. It is also drunk as a salve for the emotional pain of rejection and heartache. Alcoholi... ...teens are purchasing alcoholic beverages from irresponsible storeowners. In 1997, it was recorded that 56% of eighth graders have tried alcohol, as well as 71% of tenth graders, 80% of twelfth graders, rising to 88% in college students. These are large numbers when stated that the legal drinking age in almost all fifty states is twenty-one. In conclusion, the public as a whole needs to learn when enough is enough. It is fine to drink, but the key is to drink in moderation. People should not allow themselves to get ?totally trashed? or ?ridiculously wasted?, but drink with maturity. It is not a crime to get drunk, it is the things one does when he/she becomes intoxicated that will get them incarcerated. People will always drink, but there need to be strict laws enforced for the punishment of those who choose not to be responsible while under the influence.

Nucor Essay -- essays research papers

Business Summary and Strategy Nucor is the largest steel manufacturer in the United States. It remains a profitable company despite being in one of the most cyclical industries in the economy. Nucor enjoys this success for several reasons, employee relations, quality, productivity, and aggressive pursuit of innovation and technical excellence. Nucor's strategy is that of a low cost provider, they know they are selling a commodity and understand their competitive edge in the industry is lowering prices through innovation and productivity. The company operates primarily in two business areas, steel mills and steel products. Steel Industry Outlook Driving Forces: „Â « Globalization - Low cost foreign manufacturers "dumping" steel in the U.S. and other markets. „Â « Changes in the economy „Â « Changes in currency valuations „Â « Input/raw material prices Key Success Factors: „Â « Technological innovation such as the strip casting technology, investing in technology such as this allows Nucor to take calculated risks to ultimately lower their cost to produce steel subsequently raising margins. They now own the U.S. and Brazil rights to this technology. „Â « Employee relations - Nucor employees are more productive, loyal and Nucor has lower employee cost than competitors. „Â « Global Economic growth - if global and U.S. growth continue, Nucor will continue growth. „Â « Product Quality - Nucor has a reputation for quality products. „Â « Market S...

Cristina Garcias Dreaming in Cuban Essay -- Cristina Garcia Dreaming

Cristina Garcia's "Dreaming in Cuban" The cyclical nature of time and the supernatural are recurring themes in Cristina Garcà ­a's 'Dreaming in Cuban'. Throughout the book, the members of the del Pino family find themselves reliving the same events and situations. This is characterized by the repetition of mental illness, attempted suicide, personal exile, and lovesickness that occurs over three generations. Celia, realizes that time will continue to repeat itself unless the family history is documented and carried on. She takes the responsibility of writing letters to her lover, in order to record their story, but understands more must be done, 'memory cannot be confined' (47). When Pilar is born she is endowed with specific gifts that will enable her to carry on the del Pino family history and end the vicious cycle that consumes the family. Through supernatural forces that manifest themselves as extraordinary memory, telepathy and dreams that serve as premonitions, Pilar is lead to return to Cuba where she fulfi lls her predetermined destiny; learning the del Pino family history and ending the cycle of lost memory that consumes them. Early on, as a child growing up in Cuba, Pilar has a very firm connection with the supernatural; she is able to will things to happen using her thoughts. She imagines her nannies? hair falling out strand by strand. We discover that in fact, many of her nannies fled her home with bald patches, claiming she was possessed. Pilar also has the extraordinary ability to recall events that occurred during two years she spent on the island and during her youth in New York City. ?I was only two years old when I left Cuba but I remember everything that?s happened to me since I was a b... ...suicide. When Pilar finally learns the del Pino family history, she frees Celia from the burden of her memories. ?As I listen, I feel my grandmother?s life passing to me through her hands? (222). This act, allows Celia to ?give herself to passion? (231). The act of suicide releases her from the pain and solitude of her memories which have plagued her since her youth. In her final moments, before her death, releasing the pearl earrings to the sea, allow her the closure that she has desperately yearned for. She is only able to accomplish this through Pilar?s gifts, extrodinary memory, premonitions and telepathy have allowed her to avoid the circular cycle of time that has destroyed the del Pinos before her. With this knowledge she too can break free from her family?s mistakes. Works Cited: Garcia, Cristina. Dreaming in Cuban. New York: Ballantine, 1992.

Project Management Student

Table of contents Contents page number Executive summary Introduction Problem identification Case analysis Question 1 Question 2 Question 3 Question 4 Conclusion and Recommendations Bibliography EXECUTIVE SUMMARY Polk County is a scarcely populated County in the state. The roads are in a very poor condition and the Transportation Department supervisor, JR has been tasked to manage all the three projects: * The entrance to the Big John’s superstore ELK Mountain road * Bridge on County road 1045 The writer will analyse the case, evaluate the alternatives and propose a solution for the case that would benefit the Polk County Transportation Department to execute their projects effectively. Various models and literature will be used to motivate the assertions. INTRODUCTION Polk County is the largest county in the state it is governed by three-member Board of commissioners: Harold, Richardson and Thomas.The state faces a challenge of delivering critical projects which involve impro vements to the local roads which at the current state have put the local residents as well as tourists at risk because they are dilapidated, worn out and inadequate for purpose generally being unsafe for use. This challenge is due to many projects competing over limited resources. The three projects are: * The entrance to Big John’s Superstore * Elk Mountain road Crockett Creek bridge on the country road 1045 near prison The reasecher will analyse the case evaluate it, systematically prioritise the steps to be taken on the approach to successfully propose a solution which will benefit the Transportation Department, Polk municipality and ultimately the community at large. Various shortfalls are evident in the current Polk county municipality. The researcher will discuss them in depth with reference to various models and literatures as well as assumptions to back up the recommendations, below are the identified shortfalls: * No poor project office Funds are very limited to kick start projects that would add value to the community and improve their safety. * The tax is minimal to sustain the developments * Insuffient or no fundraising initiatives * High rate of crime As depicted on the case, there are three projects at hand and below is the gathered information on each project. Body governing the county The following individuals comprise the Polk County administration team NAME | DESTINATION/ STATUS| Thomas| Commissioner retired| Herald| Commissioner retired|Richardson| commissioner| JR| Supervisor- Transport Department| Joe| Former head of Transport Department| Unnamed | Current Senator| Zachary | Transport Department intern (civil engineering)| PROJECT 1 THE ENTRANCE TO THE BIG JOHN’s SUPERSTORE * It is off a two lane high at the base of the hill * It is difficult for cars travelling in the opposite direction until they come over the crest * This makes it difficult for the cars turning left into the store and those pulling out of the parking lot. * A number of accidents have occurred The number of cars travelling on the road has increased over the last three years since the store opened * Several residents have raised concerns at the commissioners meetings in the past * JR had approached the store manager about helping to pay for road improvements to widen the roads to add a turning lane or install a traffic light. * The manager replied that they are barely making any profit and if they do not make profit corporate headquarters will close it down and a lot of people will lose their jobs therefore they cannot afford to assist * Many people go to the store because there are no other shopping malls in the countyPROJECT 2 WIDENING AND REPAIR OF ELK MOUNTAIN ROAD IN THE NORTHWESTERN PART OF THE COUNTY * The winters have taken their toll on the road and left it with large deep potholes * The increase in unemployment in the county has led to an increase in independent loggers using the road to bring logs from Elk Mountain to severa l saw mills, including Ye Olde Saw mill in the adjacent county. The lack of repair over the years and the heavy trucks are causing the road to deteriorate even faster Both commissioners, Thomas and Richardson have seen the worsening condition of the road: they use it frequently to go hunting and fishing on ELK Mountain. * Each has received an earful of complaints from friends who use the road. * Zachary also knows how bad the road is from personal experience as he was nearly sideswiped by the logging truck and was forced off the resulting in his car’s low hanging tail pipe and muffler ripped off as he hit a large pothole.PROJECT 3 CROCKETT CREEK BRIDGE ON COUNTY ROAD 1045 NEAR THE PRISON * It is the main road to the state correctional Institution in the south western past of the county. * The bridge barely passed the last state inspection four years ago. * Each spring during the winter thaw Crockett Creek threatens to wash the bridge. * If the bridge is washed out or closed, the detour would be nearly 15 miles for people who work at the prison. * The largest employer in the county is the state correctional institution for female offenders located in the south western part of the county.A project is an endeavour to accomplish a specific objective through a unique set of interrelated tasks and the effective utilisation of resources (Clement and Gido, 2012; 4) It has a clear objective of what is to be accomplished and this is usually defined in the form of deliverable, schedule and budget. A project utilises various resources to carry out interdependent task that need to be accomplished in a certain sequence in order to achieve a project objective within a specific time frame. A project has a sponsor who provides the funds necessary to accomplish the project.A project usually has challenges because it is constrained by many factors including scope, quality budget and risks. 1. SITUATION ANALYSIS 1. 1. NO PROPER PROJECT OFFICE Polk County is the largest cou nty in the state with a shallow structure of Authority. This is evident as the line of command is very short from the top, senator, commissioner to bottom lower management this could be of advantage as there is rapid communication hence close interactions and therefore easy delivery of organisational / municipality goals strategy. JR is the supervisor for the county Transportation Department.The case states that county roads have progressively deteriorated and several critical projects need to be done. He works with his summer intern Zachary and is concerned that if the does not present a good case for the at least one of the project, then the commissioners probably would not fund any of the project. It is evident that JR is struggling as he cannot apply himself explicitly on the tasks at hand as he lack the skills, methodologies that would easily aid to address the projects smoothly, this therefore calls for the introduction of project management office in the municipality 1. 2PROJ ECT MANAGEMENT OFFICEProject management is defined by the PMBOK as†¦. ’the application of knowledge, skills, tools and techniques in order to meet stakeholder’s needs and expectation from a project. ’ (Burke, 2011; 18) 1. 3GENERIC ROLES OF A PROJECT MANAGEMENT OFFICE 1. 3. 1The project management office’s aim is to link individual project to the organisation’s dynamic strategic intent through a focused discipline of project management. 1. 3. 2The project management office is established to act as support and reporting channel between projects and senior management without removing the accountability or authority of project managers. . 3. 4The project management office provides top management with a consolidated view on all projects within the organisation and thus assists top management in ensuring that all projects are aligned with the strategic direction of the organisation. 1. 3. 5The project management office will provide value-added assis tance to all its identified customers in the organisation. 1. 3. 6The project management office will enable support and facilitate project disciplines with a: * A project life cycle Programme/project management * Project management training * Prioritisation support * Project start-up workshops and project administration ‘With the budget situation JR is worried that none of the projects may get done’, the case reads, this emphasises how the department is financially constrained and several projects are competing over this limited funds. The project management office is equipped with tools and techniques which provide a systematic approach on every project. The PMBOK states ‘†¦.Because projects are unique and involve a certain degree of risk, companies performing projects will generally subdivide their project into several project phases to provide better management control. Collectively these project phases are called the project lifecycle’. (Burke, 201 1; 40) The general project life cycle has four phases: * Concept or initiation phase * Design or planning phase * Implementation or performing phase * Commissioning and handover or closing phase In the initiating phase, projects are identified and selected. They are then authorised using a document referred to as a project charter.The planning phase includes defining the project scope, identifying resources developing a schedule and budget and identifying risks all of which makes up a baseline plan for doing the project work. In the performing phase the plan is executed and work tasks are carried out to produce all the project deliverables and to accomplish the project objective. During this phase the project progress is monitored and controlled to assure the work remains on schedule and within budget, the scope is fully completed according to specifications and all the deliverables meet the acceptance criteria.Also any changes need to be documented, approved and incorporated into a n updated baseline plan if necessary. In the closing phase the project evaluations are conducted lessons learned are identified and documented to help improve performance on future projects and project document are organised and archived. (Clement and Gido, 2012; 9) Phases in a project lifecycle are interrelated which means the previous phase should be successfully completed before progressing to the next phase.In this particular case, JR, the supervisor at a Transportation Department is struggling to make a selection on a project to perform first since there are limited funds. The main focus of this case is based on the initiation phase of the project lifecycle and because of the interrelation of the phases; it has to be successfully completed to move forward to the next phase of project. The initiation phase of the project lifecycle starts with recognising a need, problem or opportunity for which the project or projects are identified to address.Projects are identified in various ways: during an organisation strategic planning, as part of its normal operations, in a response to unexpected events or as a group of individuals deciding to organise a project to address a particular need. It is important to try to quantify the need to help evaluate whether the expected benefits from implementing a project outweigh the costs or consequences of conducting the project. Once the magnitude and the expected benefit or improvement has been estimated the cost for a project to implement the improvement. The transportation epartment of Polk County identified several needs but have limited funds and people available to pursue the projects to address those identified needs. In this case the department must go through a decision making process to prioritise and select the project that will result in the greatest overall benefit. Project selection is making a commitment for the future. The execution of a project will tie up the company resources and as an opportunity cost, the selection of one project may preclude your company from pursuing another (perhaps more profitable) project.We live in a world of finite resources and so cannot carry out all the projects we may want or need. Therefore a process is required to select and rank projects on the basis of their beneficial change to a company. (Burke, 2011: 66). The steps in the project selection process include: * develop a set of criteria against which the project will be evaluated * list assumptions that will be used on the basis of each project * Gather data and information for each project to help ensure an intelligent decision regarding project selection.Methods of gathering this information could include surveys, focus groups, interviews or analysis of available reports * Evaluate each project against criteria. Once all the data and information have been collected analysed and summarised for each potential project it should be given to all the people responsible for performing the evaluation. It is beneficial to the have several individuals in the evaluation and selection process in order to get various viewpoints.Each person on the evaluation and selection committee should have a different background and experience to bring to the decision making process, (Clement and Gido, 2012:35) emphasises that although it may take longer and be more stressful to gain group consensus on projects priorities and selections it will most likely be a better quality decision than if the decision is made by just one individual. The committee may develop a set of evaluation criteria with some type of rating system (such as Low-Medium-High, 1 to 5) against which to rate each potential project against each criterion.Various models can be used in project selection. The main purpose of these models is to aid decision making leading to project selection. The models include: * Numeric models * Non- numeric models A numeric model is usually financially focused and quantifies the project in terms of tim e to repay the investment or return on investment while non-numeric models look at a much wider view of the project considering items such as market share, relocation or environmental issues. Most importantly the models must evaluate projects by how well they meet the company’s strategic goals and corporate mission. 2.NUMERIC MODELS The numeric selection models may be subdivided into financial models and scoring models. The financial models are: * Payback period * Return on investment * Net present value * Internal rate of return Companies tend to prefer financial models and often select solely on profitability. 2. 1SCORING MODELS The numeric models mostly have common limitation, they only look at the financial element of the project. In an attempt to broaden the selection criteria, (Burke, 2011:79) suggest ‘a scoring model called the factor model, which uses multiple criteria to evaluate the project will be introduced’.The factor model simply lists a number of d esirable factors on a project selection pro-forma along with columns to show the rating of each factor. A weighted column can be added to increase the score of important factors while reducing the scoring of the less important. The advantages of using a scoring model are; * It encourages objectivity in decision making * It uses multiple selection criteria to widen the range of evaluation * It uses the simple structure therefore easy to use It uses selection factors structured by senior management, this implies that they reflect the company’s goal and objectives * It makes it easy to change factors. * It uses weighted scoring to reflect the factor’s differential importance * It is not biased towards short run projects favoured by financial models. * It is a weighted model which can also be used as a flag to improve projects by identifying the variance between the factor score and the maximum possible score The disadvantages of using a scoring model are: If the factors a re not weighted they will all equal importance * A simple model may encourage the developments of long lists that could introduce trivia factors and therefore waste management time. Assuming that the county Transportation Department has a budget of hundred million pula (P100  000) to allocate over the three project the researcher has used a scoring model to score some desirable factors on each project. This analysis and evaluation determines which project is critical and assist the project manager to prioritise effectively on which project to perform first followed by others.The figure below shows the factor scoring model for a county Transportation Department. SCORING FACTOR MODEL – PROPOSED SOLUTION| | FACTORS| PROJECT 1| PROJECT 2| PROJECT 3| 1. BENEFITS| 8| 9| 9| alignment to organisation strategy, mission, visions, values|   | 4| 4| 4| impact (organisational Department County)|   | 4| 5| 5|   |   |   |   | 2. COSTS| 4| 6| 8| budget (impact on budget)| 2| 3| 4| expenditure| 2| 3| 4| |   |   |   | 3. TIME| 7| 6| 7| delivery(how long will it take to deliver value to the community| 4| 3| 3| start- up (when can the project start)| 3| 3| 4|   |   |   | 4. RISKS| 5| 7| 9| safety and health (stakeholder and community| 3| 4| 5| environment| 2| 3| 4| |   |   |   | 5 RESOURCES| 7| 7| 8| capacity (at your disposal)| 4| 4| 4| availability| 3| 3| 4| |   |   |   | 6. STAKEHOLDERS| 5| 6| 9| commitment| 2| 3| 4| reputation| 3| 3| 5| TOTAL| 36| 41| 50| PERCENTAGE| 60| 68. 33| 83. 33| Key 5= very good weighting 4= good 0-40% low priority 3=fair 41-60% average priority 2= poor 61- 80% high priority 1= very poor 81- 100%very high priorityA priority list of projects from the model depicts Crockett Creek Bridge on road 1045 will progress under the current budget, if enough funds will be secured. ELK mountain road will follow then lastly the entrance to the Big John’s superstore. Therefore the researcher recommends that the cou nty Transport Department should adopt the project management approach by introducing a project management office. The project management office will be merged into the current county municipality opening structure to undertake all the projects across all departments with expertise.A project will be allocated a project manager and through his knowledge and skills. A methodological approach of project management will be applied. From project initiation phase are identified and selected through planning phase which involves defining the project scope, identifying resources, developing a schedule and budget and identifying resources development risks to the performing phase whereby the plan is execute and finally the closing phase/ project handover where the project lifecycle terminates.This methodological approach would be suitable for Polk County Transportation Department as projects would be executed effectively and effectively. To generate funds for the county, the commissioners can come up with initiatives like introducing road levy, introducing toll gates as well as adjusting tax higher so as to acquire funds for local developments. The crime rate is also igh as the case states that the largest employer is the state correctional institution for female offender, therefore prison as an offenders rehabilitation centre with skills they acquire during their serving period, prisoners can produce goods that can be sold to the local community to generate funds which could assist with the developments. CONCLUSION Polk County faces a problem of under development or road improvement because of limited funds. Multiple projects have been identified to address the current situation, besides the limited funds inadequate skills and lack of proper facilities have been identified.The writer analysed the case, quantified case data, evaluated it and suggests that introduction of project management office in the Polk county municipality would highly benefit the organisation as a proper systematic methodology of project management will be used to tackle and manage all projects effectively and also various fund raising initiatives will be implemented to raise money for the local government for developments. BIBLIOGRAPHY 1. Burke, R. 2011, Project Management Techniques, ( College Edition), China, Burke Publishing 2. Clements, J. P. and Gido J. 2012 Effective Project Management Fifth Edition, Canada. Joe Sabatino

MBIT: What is self-awareness? Essay

self-importance knowingness represents an saying of our individualality or the self. It includes the translateing and discovery of ones strengths, weaknesses, likes and dislikes. Others include understanding our attitudes, values and beliefs. Self-awareness de nones our knowingness and recognition of our self history (Smith, 2008). This room that we understand that we are the alike person over beat and that we can cite thoughts and actions that we ourselves do. Self awareness is directly related to to our ability to tell. Self awareness is in reality developed during our chat with ourselves and an early(a)(prenominal)s.It is during colloquy that we accept about what others think about us and what reactions and significance we are presumable to origin during converse. The Barnlunds model illustrates two types of dialogue the intrapersonal and the interpersonal communication (Smith, 2005). Intrapersonal communication which is communication with ones self helps to tally out our innermost qualities through with(predicate) our perceptions, evaluations, inferences, ideas, evaluations and memories. interpersonal communication which refers to communication with others helps us to understand other spate and at the same time discover our strengths and weaknesses.It is that through self-awareness that we can be able to go on effectively. Self awareness is what enables us to be more strategic in our communication practices. According to Smith (2005), it is only when we understand ourselves that we can be able to infer and control how we devolve. Understanding others is also essential in our communication and this can only be achieved if we understand ourselves first. For example, a person who does not return self awareness is likely to face challenges when communicating with other people because he is likely to misunderstand other peoples responses to his or her messages.If we do not interact with others and ask our strengths and weaknesses a nd the contradictions that exist between individuals we whitethorn not be able to change our communication behaviors to better express ourselves (Smith, 2005). I have come to realize that my spirit whitethorn not always allow me to nab along with everyone. I am ESFJ accord to the MBIT personality tool. I am fairly convey extravert, slightly expressed sensing, moderately expressed feeling and slightly expressed judging. Since I have more of an modal(a) personality, I would have difficulties dealing with rough personalities such as the ENTJs.ENTJs will race to have difficulty seeing things from other peoples perspectives and more likely than not they get impatient whenever others do not see things their way. Better communication with such mannikin of people would call for proper understanding of their personality and and then trying to solve any kind of misunderstanding by expressing my call for of clear to them. I am slightly expressed extravert which means that I slan g energy from action. I prefer affect information through conversing and idleness or inactivity tends to lower my motivation.I am likely to work with introverts who whitethorn not be as energetic and who prefer to reflect forward acting. I may find that I cannot easily communicate or brainstorm with these kind of people in order to come up with ideas. To deal with this, I would have to be more patient with these peoples personalities. It may mean giving my point of view and then giving them time to act on the idea before making a plausible solution. I tend to bring stopping points by empathizing with a built in bed, considering the people involved in the situation and taking a solution that brings great consensus.My feelings and personal values must be involved in making burning(prenominal) decisions. At my work place, I may meet people who are cerebration (T) instead of feeling (F) as I am. These ones tend to make decisions based on what is reasonable and logical depending on the compendium of the situation. To better interact with these kinds of people, understanding of their personality is essential and sharing my ideas with them will make them understand me better. That way, we can effectively communicate and respect each others way of decision making.Word Count667 Reference Smith, T. R. (2005). MBIT On the Path to Self Awareness. London clear-sighted

Intertextual Relationship Between Renoir’s Parte de Campagne Essay

The usage of Mohandas Gandhi greatly affected martin Luther Kings writing , particularly in the region of nonviolent opposition.However they had already laid the solid bedrock for the advancement of the film industry and other pioneers took it in the 1930’s. (Hortelano, 2011, p.256)While during the First World War, the cinema industry seemed to have grounded to a halt, the period after 1920 going to 1930’s show gradual emergence of younger film directors with much enthusiasm in the industry. Such included Marcel Carne, Rene Clair logical and Jean Renoir (Conley 2007 p.Theyre also in applying the preparation methods superior subject matters.This included among others, Jacques Rivette, little Jean lucques Godard, Loius Malle, Francois Truffaut and Alain Resnais. This group of thin film makers believed that a filmmaker has possession of the film without interference from either studios or producers. This paper will discuss Partie de Campagne and Les Mistons., twenty tw o films made by two great French film makers, Jean Renoir and vitry Francois Truffaut respectively.

Throughout your education, you need to write essays.However, despite it being unfinished, it was released ten years down the line. Renoir is famed for producing films with lots of critical realism and satirical content (Hortelano, 2011, p.257). Just like Truffaut’s film, the film Parte de Campagne is a romance filled film based on a short story by Guy de Maupassant and the plot of the film revolves around a family that decides to give take sometime in the country side.When youre in possession of a strong thesis, then you will start to compose the article and ve fully improved your article topic.The former lover, George Saint-Saens, undertook to renew the initial relationship great but to no avail. They both try to catch up but the family large heads to the city. Episodes on what happened were never shot as the project was abandoned (Miller, 2006, p.5) Exemplar, the shots of the late summer storm and the long sequence of the rain firing the river that, underlying the expl osion of passion of the only natural element, and between Henry and Henriette.

He keeps close to Maupassant narratives events.258).On the other hand, Truffaut’s Les Mistons delves onto the lives of children. It was shot in 1957, when Truffaut was only twenty five years old. Unlike Renoir, Truffaut represents the second phase of original French new wave in the cinema industry.Intertextuality has been used by writers as a device for a means to bring forth references to other functions that might help to construct the affect his full text is wanted by the author.Bernadette is the origin and object of a prestigious discovery, symbol of a bright sensuality, mysterious and fascinating personification of the full dark dreams and secret imaginations that populate the nights of adolescents in NÃ ®mes.She becomes the victim of a hostile crowd as soon as the brats learn the impossibility to possess the object of desire, the sense of their strangeness as jealous witnesses, forced to only spy kisses and desire hoped tenderness. The camera takes on this helples s anger, clutching complimentary close behind the five Mistons, following them lovingly. The destruction of the couple has a remote character, is projected worn out of the exclusive world of adolescents: there is just a little bitterness, pity perhaps, only as a memory of the adventures of adolescence.

Dialogism is a form of intertextuality though the expression was coined decades after dialogism.He attempted to make the film as sensuous as possible using affects such as reverse motion and slow motion in for first instance the scene where Gerald is seen kissing Bernadette on the balcony (Dixon, 2006, p.6). Just like his hero Renoir, the shooting of the film was grounded for some time, as the cast took a ten days break logical and came back to continue as if nothing had happened. Being twenty five years then, it captures the moment of the time as it displays his love for the american youth and relationships.From here, you have to develop your own topic that is specific that is under how this overall idea.So well was the synchronization that any boy chosen to appear on the scene would be seen to be representative of the entire idea of all boys’ infatuation (Conley 2007 p.166). This is based on his approach in acquiring the cast where he conducted interviews with boys in the age bracket eleven to fourteen, where he was looking for raw talent and best best fits into the cast rather than theatrical experience. His desire to grow and uplift young people old saw him recruit a young person for the position of director of production, his friend logical and collaborator Bazin (Dixon, 2006, p.

Movie directors may be thought to how have invented the notion of cinema.In fact, one of the boys out of the cinema rips the poster while the others 3rd sing Colliers perdus sans chiens, reversing the lyrics of Paul Edmond Bacri Misraki which is part of the musical soundtrack of the film by Delannoy.Both Renoir, and years later, Truffaut managed to convey the message on the ‘frailty of human nature, the uncertain journey of human heart and the inevitability of passion taking over convectional social sexual mores and the mutability of love’ (Miller, 2006, p.4). Both aueturs treat similar themes in a natural framework, signature of both’s poetic realism.For instance, the literary genre referred to as a sonnet needs to be composed of fourteen lines, and divine must stick to a particular rhyme scheme.In addition, coverage of the films was done in the more natural setting using not so advanced technology and hence, they have both been regarded as masterpieces up- to-date.ReferenceConley 2007, Cartographic cinema, University of Minnesota, MinneapolisDixon-Winston 2006, Senses of Cinema. [Online]. Available at: http://sensesofcinema.

It isnt a normal romance blindly glorifying the medieval Earth .Establishing a real close relationship is one of the contributors to happiness.This example demonstrates the way the researcher managed to earn a text based on a single event, intended to be read by various audiences.The next job is to decide the role of the allusion.